EDIT: I used an original Garlic Junior image for color reference. So YES these colors are correct. The lightest color, next to the white-like highlights, is very light blue. I know my lighting and contrast is funny in this image, but I'm a funny person myself. Also, I wanted to give him a grungy/dirty villian look to him, to enhance the feel of everything...
You mentally have to think about this. About the direction of the light, his hood covering his face; I know it's odd and doesn't seem like it fits the Anime character's color, but you will learn in ART classes that you are to draw and color what you see, not what you think you know and see. Confused yet?